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Reference · Glass Transition

Tg explained.
Plastic stiffness.
Material behavior.

Glass transition temperature (Tg) reference. Plastic stiffness changes at Tg. Below: rigid. Above: flexible. Critical for service temperature.

01 · Key principles

Key principles.

Tg definition

Stiffness change

Temperature where amorphous plastic transitions stiff to flexible.

Below Tg

Rigid

Below Tg, plastic glassy and rigid. Standard service.

Above Tg

Rubbery

Above Tg, plastic rubbery. Generally avoid.

Crystalline plastics

Tm matters more

Crystalline plastics melting point (Tm) more relevant.

Common plastics

Various Tg

PC 150°C. ABS 105°C. Nylon 50-60°C. PEEK 143°C.

Specifying service

Below Tg

Service temperature below Tg. Safety margin 20-30°C.

FAQ

Why does Tg matter?

Plastic loses stiffness above Tg. Service must stay below for structural applications.

Tg vs melting point?

Tg: amorphous transition (gradual). Tm: crystalline melting (sharp). Different mechanisms.

Common plastic Tgs?

PC 150°C. ABS 105°C. Nylon (PA66) 60°C. PEEK 143°C. PVC 80°C. PS 100°C.

Service temperature?

Continuous service ≤ Tg minus 20-30°C safety margin. Structural applications.

Glass-filled effects?

Glass fiber raises effective service temperature, less Tg dependent.

Specifying for design?

Specify continuous service temperature. Material/process select per Tg.

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